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  <front>
    <journal-meta>
      <journal-id journal-id-type="publisher-id">Physical Oceanography</journal-id>
      <journal-title-group>
        <journal-title xml:lang="en">Physical Oceanography</journal-title>
      </journal-title-group>
      <issn publication-format="print">1573-160X</issn>
    </journal-meta>
    <article-meta>
      <article-id pub-id-type="publisher-id">20240605</article-id>

      <article-categories>
        <subj-group subj-group-type="toc-heading" xml:lang="en">
          <subject>Experimental and field research</subject>
        </subj-group>
        <subj-group subj-group-type="article-type">
          <subject>Research Article</subject>
        </subj-group>
      </article-categories>

      <title-group>
        <article-title xml:lang="en">Biogeochemical Characteristics of the Surface Layer and CO<sub>2</sub> Fluxes in the Ocean – Atmosphere System in the Fjords of Western Spitsbergen</article-title>
      </title-group>

      <contrib-group>
        <contrib contrib-type="author">
          <contrib-id contrib-id-type="orcid">https://orcid.org/0000-0002-0705-6408</contrib-id>
          <contrib-id contrib-id-type="researcherid">J-5432-2016</contrib-id>
          <name>
            <surname>Alekseeva</surname>
            <given-names>N. K.</given-names>
          </name>
          <address>
            <country country="RU">Russian Federation</country>
          </address>
          <email>nkalekseeva@aari.ru</email>
          <xref ref-type="aff" rid="aff1"/>
        </contrib>
        <contrib contrib-type="author">
          <contrib-id contrib-id-type="orcid">https://orcid.org/0000-0002-7001-338X</contrib-id>
          <name>
            <surname>Nikulina</surname>
            <given-names>A. L.</given-names>
          </name>
          <address>
            <country country="RU">Russian Federation</country>
          </address>
          <email>anikulina@aari.ru</email>
          <xref ref-type="aff" rid="aff1"/>
        </contrib>
        <contrib contrib-type="author">
          <contrib-id contrib-id-type="orcid">https://orcid.org/0000-0002-2078-7459</contrib-id>
          <contrib-id contrib-id-type="researcherid">I-6901-2015</contrib-id>
          <name>
            <surname>Bloshkina</surname>
            <given-names>E. V.</given-names>
          </name>
          <address>
            <country country="RU">Russian Federation</country>
          </address>
          <email>bloshkinaev@mail.ru</email>
          <xref ref-type="aff" rid="aff1"/>
        </contrib>
        <contrib contrib-type="author">
          <contrib-id contrib-id-type="orcid">https://orcid.org/0009-0009-2985-7570</contrib-id>
          <contrib-id contrib-id-type="researcherid">HPE-4386-2023</contrib-id>
          <name>
            <surname>Shved</surname>
            <given-names>Ya. V.</given-names>
          </name>
          <address>
            <country country="RU">Russian Federation</country>
          </address>
          <email>yvswede@aari.ru</email>
          <xref ref-type="aff" rid="aff1"/>
        </contrib>
        <contrib contrib-type="author">
          <contrib-id contrib-id-type="orcid">https://orcid.org/0009-0008-8300-6550</contrib-id>
          <name>
            <surname>Ryzhov</surname>
            <given-names>I. V.</given-names>
          </name>
          <address>
            <country country="RU">Russian Federation</country>
          </address>
          <email>ryzhov@aari.ru</email>
          <xref ref-type="aff" rid="aff1"/>
        </contrib>
        <contrib contrib-type="author">
          <contrib-id contrib-id-type="orcid">https://orcid.org/0000-0001-5141-8624</contrib-id>
          <contrib-id contrib-id-type="researcherid">J-6005-2016</contrib-id>
          <name>
            <surname>Novikhin</surname>
            <given-names>A. E.</given-names>
          </name>
          <address>
            <country country="RU">Russian Federation</country>
          </address>
          <email>andrey_n@aari.ru</email>
          <xref ref-type="aff" rid="aff1"/>
        </contrib>
        <contrib contrib-type="author">
          <contrib-id contrib-id-type="orcid">https://orcid.org/0000-0002-2801-1030</contrib-id>
          <contrib-id contrib-id-type="researcherid">K-8861-2016</contrib-id>
          <name>
            <surname>Makhotin</surname>
            <given-names>M. S.</given-names>
          </name>
          <address>
            <country country="RU">Russian Federation</country>
          </address>
          <email>makhotin@aari.ru</email>
          <xref ref-type="aff" rid="aff1"/>
        </contrib>
      </contrib-group>

      <aff id="aff1">
        <institution>Arctic and Antarctic Research Institute</institution>
        <addr-line>Saint-Petersburg</addr-line>
        <country country="RU">Russia</country>
      </aff>

      <pub-date date-type="pub" iso-8601-date="2024-12-31" publication-format="electronic">
        <day>31</day>
        <month>12</month>
        <year>2024</year>
      </pub-date>
      <volume>31</volume>
      <issue>6</issue>
      <fpage>826</fpage>
      <lpage>837</lpage>

      <history>
        <date date-type="received" iso-8601-date="2024-06-26">
          <day>26</day>
          <month>06</month>
          <year>2024</year>
        </date>
        <date date-type="rev-recd" iso-8601-date="2024-08-21">
          <day>21</day>
          <month>08</month>
          <year>2024</year>
        </date>
        <date date-type="accepted" iso-8601-date="2024-09-12">
          <day>12</day>
          <month>09</month>
          <year>2024</year>
        </date>
      </history>

      <permissions>
        <copyright-statement xml:lang="en">Copyright ©; 2024, N. K. Alekseeva, A. L. Nikulina, E. V. Bloshkina, Ya. V. Shved, I. V. Ryzhov, A. E. Novikhin, M. S. Makhotin</copyright-statement>
        <copyright-year>2024</copyright-year>
        <copyright-holder xml:lang="en">N. K. Alekseeva, A. L. Nikulina, E. V. Bloshkina, Ya. V. Shved, I. V. Ryzhov, A. E. Novikhin, M. S. Makhotin</copyright-holder>
        <ali:free_to_read xmlns:ali="http://www.niso.org/schemas/ali/1.0/"/>
        <license>
          <ali:license_ref xmlns:ali="http://www.niso.org/schemas/ali/1.0/">https://creativecommons.org/licenses/by-nc/4.0/</ali:license_ref>
        </license>
      </permissions>

      <self-uri xlink:href="https://physical-oceanography.ru/repository/issues/2024/06/05/" xlink:title="Article page">https://physical-oceanography.ru/repository/issues/2024/06/05/</self-uri>

      <abstract xml:lang="en">
        <p><bold>Purpose.</bold> The study is purposed at assessing and analyzing spatial variability and seasonal dynamics of the carbonate system parameters in the fjords of Western Spitsbergen based on the results of field research in the spring (April) and summer (August) seasons, 2023.</p>
        <p><bold>Methods and Results.</bold> The physical and chemical parameters of water, such as total alkalinity, pH and nutrient contents were studied. The samples were analyzed in the chemical analytical laboratory of the Russian Scientific Center at Spitsbergen (RSCS). The pH was measured using a Mettler Tolledo Seven Compact S220 laboratory pH-meter, and total alkalinity -- by direct titration of a seawater sample with a 0.02 hydrochloric acid (the equivalence point was determined visually). The concentrations of phosphates and silicates, as well as chlorophyll <italic>a</italic> were measured by standard spectrometric methods. The carbonate system parameters and CO<sub>2</sub> flux direction and speed were calculated using the <italic>Program Developed for</italic> CO<sub>2</sub> <italic>System Calculations</italic>. The revealed seasonal dynamics and variability of the carbonate system parameters are closely related to the atmospheric conditions, water mass seasonal variability and intensity of bioproductivity. The estimates of carbon dioxide flux obtained using the data for August 2023 allow to conclude that during this period CO<sub>2</sub> is absorbed in Grønfjorden (−1.52 … −4.76 mmol m<sup>−2</sup>·day<sup>−1</sup>) and Isfjorden (−0.12 … −1.0 mmol m<sup>−2</sup>·day<sup>−1</sup>), whereas in Billefjorden a local area with positively directed CO<sub>2</sub> flux (1.2–2.6 mmol m<sup>−2</sup>·day<sup>−1</sup>) was discovered.</p>
        <p><bold>Conclusions.</bold> The studies carried out in the fjords have resulted in revealing seasonal fluctuations in the carbonate system parameters and the carbon dioxide fluxes similar to other inner fjords of Spitsbergen. The obtained results highlight the importance of the carbonate system parameters in understanding the biogeochemical balance and the state of marine ecosystems in the context of climate change.</p>
      </abstract>

      <kwd-group>
        <kwd>Western Spitsbergen fjords</kwd>
        <kwd>marine carbonate system</kwd>
        <kwd>CO<sub>2</sub> flux</kwd>
        <kwd>chlorophyll <italic>a</italic></kwd>
        <kwd>aragonite</kwd>
        <kwd>Arctic</kwd>
      </kwd-group>

      <funding-group>
        <funding-statement xml:lang="en">The material was collected by the Arctic and Antarctic Research Institute (AARI) at Spitsbergen within the framework of the Russian Scientific Arctic Expedition to Spitsbergen (RAE-S) in 2023. The authors are grateful to the RAE-S Research Coordination and Planning Department for their constant attention to the work and high-quality organization of field studies, as well as to the RAE-S wintering team in Barentsburg for their assistance in field and laboratory research. The study was carried out within the framework of the Federal Scientific and Technical Program in the field of ecological development of the Russian Federation and climate change for 2021–2030. Agreement No. 169-03-2024-072.</funding-statement>
      </funding-group>
    </article-meta>
  </front>

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    <p>Article text not included.</p>
  </body>

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