<?xml version="1.0" encoding="UTF-8"?>
<!DOCTYPE article PUBLIC "-//NLM//DTD JATS (Z39.96) Journal Publishing DTD v1.3 20210610//EN" "JATS-journalpublishing1-3.dtd">
<article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" article-type="research-article" dtd-version="1.3" xml:lang="en">
  <front>
    <journal-meta>
      <journal-id journal-id-type="publisher-id">Physical Oceanography</journal-id>
      <journal-title-group>
        <journal-title xml:lang="en">Physical Oceanography</journal-title>
      </journal-title-group>
      <issn publication-format="print">1573-160X</issn>
    </journal-meta>
    <article-meta>
      <article-id pub-id-type="publisher-id">20250606</article-id>
      
      <article-categories>
        <subj-group subj-group-type="toc-heading" xml:lang="en">
          <subject>Experimental and field research</subject>
        </subj-group>
        <subj-group subj-group-type="article-type">
          <subject>Research Article</subject>
        </subj-group>
      </article-categories>

      <title-group>
        <article-title xml:lang="en">Hydrochemical Characteristics of the Novorossiysk Port Waters (Black Sea) in 2011</article-title>
      </title-group>

      <contrib-group>
        <contrib contrib-type="author">
          <contrib-id contrib-id-type="orcid">https://orcid.org/0000-0002-6595-6172</contrib-id>
          <name>
            <surname>Matishov</surname>
            <given-names>G. G.</given-names>
          </name>
          <address>
            <country country="RU">Russian Federation</country>
          </address>
          <email>ssc-ras@ssc-ras.ru</email>
          <xref ref-type="aff" rid="aff1"/>
        </contrib>
        <contrib contrib-type="author">
          <contrib-id contrib-id-type="orcid">https://orcid.org/0000-0003-4774-4835</contrib-id>
          <name>
            <surname>Stepanyan</surname>
            <given-names>O. V.</given-names>
          </name>
          <address>
            <country country="RU">Russian Federation</country>
          </address>
          <email>step@ssc-ras.ru</email>
          <xref ref-type="aff" rid="aff1"/>
        </contrib>
        <contrib contrib-type="author">
          <contrib-id contrib-id-type="orcid">https://orcid.org/0009-0006-6549-8606</contrib-id>
          <contrib-id contrib-id-type="spin">3063-3180</contrib-id>
          <name>
            <surname>Antsiferova</surname>
            <given-names>M. A.</given-names>
          </name>
          <address>
            <country country="RU">Russian Federation</country>
          </address>
          <email>m12antsiferova@mail.ru</email>
          <xref ref-type="aff" rid="aff1"/>
        </contrib>
        <contrib contrib-type="author">
          <contrib-id contrib-id-type="orcid">https://orcid.org/0000-0002-9014-2859</contrib-id>
          <name>
            <surname>Alyoshina</surname>
            <given-names>E. G.</given-names>
          </name>
          <address>
            <country country="RU">Russian Federation</country>
          </address>
          <email>aleshina@ssc-ras.ru</email>
          <xref ref-type="aff" rid="aff1"/>
        </contrib>
        <contrib contrib-type="author">
          <name>
            <surname>Sawyer</surname>
            <given-names>V. G.</given-names>
          </name>
          <address>
            <country country="RU">Russian Federation</country>
          </address>
          <xref ref-type="aff" rid="aff1"/>
        </contrib>
      </contrib-group>

      <aff id="aff1">
        <institution>Federal Research Center the Southern Scientific Center, Russian Academy of Sciences</institution>
        <addr-line>Rostov-on-Don</addr-line>
        <country country="RU">Russian Federation</country>
      </aff>

      <pub-date date-type="pub" iso-8601-date="2025-12-31" publication-format="electronic">
        <day>31</day>
        <month>12</month>
        <year>2025</year>
      </pub-date>
      <volume>32</volume>
      <issue>6</issue>
      <fpage>826</fpage>
      <lpage>840</lpage>

      <history>
        <date date-type="received" iso-8601-date="2025-06-02">
          <day>02</day>
          <month>06</month>
          <year>2025</year>
        </date>
        <date date-type="rev-recd" iso-8601-date="2025-06-27">
          <day>27</day>
          <month>06</month>
          <year>2025</year>
        </date>
        <date date-type="accepted" iso-8601-date="2025-09-10">
          <day>10</day>
          <month>09</month>
          <year>2025</year>
        </date>
      </history>

      <permissions>
        <copyright-statement xml:lang="en">Copyright ©; 2025, G. G. Matishov, O. V. Stepanyan, M. A. Antsiferova, E. G. Alyoshina, V. G. Sawyer</copyright-statement>
        <copyright-year>2025</copyright-year>
        <copyright-holder xml:lang="en">G. G. Matishov, O. V. Stepanyan, M. A. Antsiferova, E. G. Alyoshina, V. G. Sawyer</copyright-holder>
        <ali:free_to_read xmlns:ali="http://www.niso.org/schemas/ali/1.0/"/>
        <license>
          <ali:license_ref xmlns:ali="http://www.niso.org/schemas/ali/1.0/">https://creativecommons.org/licenses/by-nc/4.0/</ali:license_ref>
        </license>
      </permissions>
      <self-uri xlink:href="https://physical-oceanography.ru/repository/issues/2025/06/06/" xlink:title="Article page">https://physical-oceanography.ru/repository/issues/2025/06/06/</self-uri>
      <abstract xml:lang="en">
        <p><bold>Purpose.</bold> The study is aimed to investigate the hydrological and hydrochemical characteristics of seawater and bottom sediments in the Novorossiysk port area (operated by PJSC “NCSP”) and adjacent waters (the Black Sea) under anthropogenic influence during the warm season of 2011.</p>
        <p><bold>Methods and Results.</bold> Standard hydrological and hydrochemical methods were employed to analyze seawater samples. During the study period, certain parameters at individual stations exceeded the maximum permissible concentrations (MPC) for seawater in fishery water bodies. However, the average hydrochemical values across the entire port area remained within the established norms. Notably, at station 13, significantly anomalous values (compared to other stations) were observed for pH, organic carbon, oxygen, methane, and nutrient concentrations, which can be attributed to the influence of the Tsemes River runoff and wastewater discharges. The MPC in seawater were observed for methane (July), synthetic surfactants (July, September), oil products (throughout all seasons), and heavy metals: iron and mercury (throughout the entire observation period), manganese, lead, zinc (June, July) and copper (June, September). At certain stations (particularly 14 and 1), MPC exceedances for oil products and several heavy metals were recorded, while concentrations at adjacent stations were several times lower. This pattern indicates a complex hydrological regime in the port area and suggests localized sources of pollutants (primarily wastewater discharge). Bottom sediments exhibited relatively high contamination with oil products (at stations 13 and 17) and heavy metals (iron at stations 20 and 21, manganese at stations 12 and 13 and copper at station 4).</p>
        <p><bold>Conclusions.</bold> The distribution of hydrochemical parameters in the Novorossiysk port area is heterogeneous, driven by a complex interplay of hydrodynamic processes, limited water exchange with the open sea, the influence of surface freshwater runoff and biotic factors. The primary sources of pollution are point discharges associated with river runoff and sewage effluents. Although average pollution levels across the port area do not exceed regulatory standards, localized hotspots, especially near discharge points, require constant monitoring.</p>
      </abstract>

      <kwd-group>
        <kwd>hydrochemistry</kwd>
        <kwd>pollution</kwd>
        <kwd>Novorossiysk Bay</kwd>
        <kwd>Novorossiysk port</kwd>
        <kwd>Black Sea</kwd>
        <kwd>heavy metals</kwd>
        <kwd>oil products</kwd>
        <kwd>bottom sediments</kwd>
      </kwd-group>

      <funding-group>
        <funding-statement xml:lang="en">This study was conducted as part of the state assignment of SSC RAS “Southern seas of Russia and their watersheds in the context of global climatic and industrial challenges" (state registration No. 125012100503-4).</funding-statement>
      </funding-group>
    </article-meta>
  </front>

  <body>
    <p>Article text not included.</p>
  </body>

  <back>
    <ref-list>
      <title>REFERENCES</title>
      <ref id="B1">
        <label>1.</label>
        <element-citation publication-type="journal">
          <person-group person-group-type="author">
            <name><surname>Yasakova</surname><given-names>O.N.</given-names></name>
            <name><surname>Chasovnikov</surname><given-names>V.K.</given-names></name>
          </person-group>
          <article-title>Effect of Hydrochemical State on the Development of Phytoplankton in Novorossiysk Port (The Black Sea)</article-title>
          <source>Marine Ecological Journal</source>
          <year>2014</year>
          <volume>13</volume>
          <issue>2</issue>
          <fpage>90</fpage>
          <lpage>101</lpage>
          <comment>(in Russian)</comment>
        </element-citation>
      </ref>
      <ref id="B2">
        <label>2.</label>
        <element-citation publication-type="book">
          <person-group person-group-type="author">
            <name><surname>Chasovnikov</surname><given-names>V.K.</given-names></name>
            <name><surname>Yasakova</surname><given-names>O.N.</given-names></name>
            <name><surname>Berdnikov</surname><given-names>V.S.</given-names></name>
          </person-group>
          <article-title>Parameters of Hydro-Chemical Regime and State of Phytoplankton in the Waters of the Port of Novorossiysk (The Black Sea) in 2009</article-title>
          <person-group person-group-type="editor">
            <name><surname>Rudakova</surname><given-names>S. L.</given-names></name>
          </person-group>
          <source>Current Status and Methods of Studying Inland Water Ecosystems: Collection of Materials from I All-Russian Scientific Conference dedicated to the 100th anniversary of Igor I. Kurenkov</source>
          <publisher-loc>Petropavlovsk-Kamchatsky</publisher-loc>
          <publisher-name>Kamchatka Research Institute of Fisheries and Oceanography</publisher-name>
          <year>2015</year>
          <fpage>143</fpage>
          <lpage>150</lpage>
          <comment>(in Russian)</comment>
        </element-citation>
      </ref>
      <ref id="B3">
        <label>3.</label>
        <element-citation publication-type="book">
          <person-group person-group-type="author">
            <name><surname>Yasakova</surname><given-names>O.N.</given-names></name>
            <name><surname>Chasovnikov</surname><given-names>V.K.</given-names></name>
          </person-group>
          <article-title>Water Hydrochemical Structure and Phytoplankton Status in the Port of Novorossiysk in 2010</article-title>
          <source>Modern Methods and Means of Oceanological Research. Proceedings of the XV All-Russian Scientific and Technical Conference (MSOI-2017)</source>
          <publisher-loc>Moscow</publisher-loc>
          <publisher-name>IO RAS</publisher-name>
          <year>2017</year>
          <volume>1</volume>
          <fpage>310</fpage>
          <lpage>314</lpage>
          <comment>(in Russian)</comment>
        </element-citation>
      </ref>
      <ref id="B4">
        <label>4.</label>
        <element-citation publication-type="journal">
          <person-group person-group-type="author">
            <name><surname>Kondratev</surname><given-names>S.I.</given-names></name>
            <name><surname>Medvedev</surname><given-names>E.V.</given-names></name>
            <name><surname>Konovalov</surname><given-names>S.K.</given-names></name>
          </person-group>
          <article-title>Total Alkalinity and PH in the Black Sea Waters in 2010-2011</article-title>
          <source>Physical Oceanography</source>
          <year>2017</year>
          <issue>4</issue>
          <fpage>35</fpage>
          <lpage>45</lpage>
          <pub-id pub-id-type="doi">10.22449/1573-160X-2017-4-35-45</pub-id>
        </element-citation>
      </ref>
      <ref id="B5">
        <label>5.</label>
        <element-citation publication-type="journal">
          <person-group person-group-type="author">
            <name><surname>Matishov</surname><given-names>G.G.</given-names></name>
            <name><surname>Stepanyan</surname><given-names>O.V.</given-names></name>
            <name><surname>Kharkovsky</surname><given-names>V.M.</given-names></name>
            <name><surname>Soyer</surname><given-names>V.G.</given-names></name>
          </person-group>
          <article-title>Oil Pollution of Azov and Black Seas Increases</article-title>
          <source>Priroda</source>
          <year>2016</year>
          <issue>5</issue>
          <volume>1209</volume>
          <fpage>64</fpage>
          <lpage>69</lpage>
          <comment>(in Russian)</comment>
        </element-citation>
      </ref>
      <ref id="B6">
        <label>6.</label>
        <element-citation publication-type="journal">
          <person-group person-group-type="author">
            <name><surname>Nemirovskaya</surname><given-names>I.A.</given-names></name>
            <name><surname>Lisitzin</surname><given-names>A.P.</given-names></name>
          </person-group>
          <article-title>Hydrocarbons in Waters and Bottom Sediments of Coastal Areas in the Northeastern Part of the Black Sea</article-title>
          <source>Doklady Earth Sciences</source>
          <year>2015</year>
          <volume>464</volume>
          <issue>1</issue>
          <fpage>972</fpage>
          <lpage>978</lpage>
          <pub-id pub-id-type="doi">10.1134/S1028334X15090202</pub-id>
        </element-citation>
      </ref>
      <ref id="B7">
        <label>7.</label>
        <element-citation publication-type="journal">
          <person-group person-group-type="author">
            <name><surname>Bogdanova</surname><given-names>A.K.</given-names></name>
          </person-group>
          <article-title>[Wind Effected Circulation and Thermal Mode of the Black Sea]</article-title>
          <source>Trudy Sevastopolskoy Biologicheskoy Stantsii</source>
          <year>1959</year>
          <volume>11</volume>
          <fpage>262</fpage>
          <lpage>283</lpage>
          <comment>(in Russian)</comment>
        </element-citation>
      </ref>
      <ref id="B8">
        <label>8.</label>
        <element-citation publication-type="book">
          <person-group person-group-type="author">
            <name><surname>Ovchinnikov</surname><given-names>I.M.</given-names></name>
            <name><surname>Titov</surname><given-names>V.B.</given-names></name>
            <name><surname>Krivosheya</surname><given-names>V.G.</given-names></name>
            <name><surname>Udodov</surname><given-names>A.I.</given-names></name>
            <name><surname>Prokopov</surname><given-names>O.I.</given-names></name>
            <name><surname>Savin</surname><given-names>M.T.</given-names></name>
          </person-group>
          <article-title>Hydrophysical Structure and Water Dynamics (of the North Eastern Part of the Black Sea)</article-title>
          <source>Technogenic Pollution and Processes of Natural Self-Purification of the Caucasian Zone of the Black Sea</source>
          <publisher-loc>Moscow</publisher-loc>
          <publisher-name>Nedra</publisher-name>
          <year>1996</year>
          <volume>6</volume>
          <issue>1-5</issue>
          <fpage>132</fpage>
          <lpage>202</lpage>
          <comment>(in Russian)</comment>
        </element-citation>
      </ref>
    </ref-list>
  </back>
</article>
