Current Hydrochemical Regime of the Sevastopol Bay

N. A. Orekhova, A. V. Varenik

Marine Hydrophysical Institute, Russian Academy of Sciences, Sevastopol, Russian Federation

e-mail: natalia.orekhova@mhi-ras.ru

Abstract

Variability of nutrients and the carbonate system components in the Sevastopol Bay is considered based on the hydro and -chemical surveys’ data obtained in Marine Hydrophysical Institute in 2007–2016. Their inter-annual and seasonal variations are assessed proceeding from the nutrients’ data and carbonate system components. Our results permit to draw a conclusion that the anthropogenic component constitutes a predominant pressure upon the ecological state of the Sevastopol Bay. At that spatial distribution of the nutrients and the carbonate system components is also conditioned by the Chernaya River fresh waters in the inner part of the bay. It is shown that organic matter oxidation and the carbonates‘ dissolution resulting from strong eutrophication determine the modern state of the carbonate system in the Sevastopol Bay. The decreasing difference between the atmospheric and surface waters pCO2 provides the basis at which the bay ecosystem can soon become a source of carbon dioxide. The conclusion is that shift of equilibrium towards predominance of the organic component in the natural cycles, as well as the increasing anthropogenic influence upon the Sevastopol Bay ecosystem can negatively affect both its ecological and recreational status.

Keywords

Sevastopol Bay, nutrients, carbonate system

Acknowledgements

The research was carried out within the framework of the State Order No. 0827-2014-0010 “Complex interdisciplinary research of oceanographic processes determining the functioning and evolution of the Black Sea and the Azov Sea ecosystems on the basis of modern methods for marine environment monitoring and grid technologies” (“Fundamental Oceanography” code) and RFBR research project 16-35-60006 mol_a_dk “Long-term changes in the carbon cycle characteristics of the Sevastopol Bay”.

Original russian text

Original Russian Text © N. A. Orekhova, A. V. Varenik, 2018, published in MORSKOY GIDROFIZICHESKIY ZHURNAL, Vol. 34, Iss. 2, pp. 134–146 (2018)

For citation

Orekhova, N.A. and Varenik, A.V., 2018. Current Hydrochemical Regime of the Sevastopol Bay. Physical Oceanography, 25(2), pp. 124-135. doi:10.22449/1573-160X-2018-2-124-135

DOI

10.22449/1573-160X-2018-2-124-135

References

  1. Ivanov, V.A., Ovsyanyy, E.I., Repetin, L.N. and Romanov, A.S., 2006. Gidrologo-Gidrokhimicheskiy Rezhim Sevastopol'skoy Bukhty i ego Izmeneniya pod Vozdeystviem Klimaticheskikh i Antropogennykh Faktorov [Hydrological-Hydrochemical Regime of the Sevastopol Bay and its Changes under the Influence of Climatic and Anthropogenic Factors]. Working paper. Sevastopol: MHI, 90 p. (in Russian, unpublished).
  2. Orekhova, N.A. and Konovalov, S.K., 2009. Polarography of the Bottom Sediments in the Sevastopol Bay. Physical Oceanography, [e-journal] 19(2), pp. 111-123. https://doi.org/10.1007/s11110-009-9038-6
  3. Moiseenko, O.G. and Orekhova, N.A., 2011. Investigation of the Mechanism of the Long-Term Evolution of the Carbon Cycle in the Ecosystem of the Sevastopol Bay. Physical Oceanography, [e-journal] 21(2), pp. 142-152. https://doi.org/10.1007/s11110-011-9111-9
  4. Orekhova, N.A., 2010. Gipoksiya i Anoksiya v Donnykh Osadkakh Krymskogo Poberezh'ya [Hypoxia and Anoxia in Bottom Sediments of the Crimean Penensula]. Geography and Tourism, [e-journal] (4), pp. 146-152 (in Russian).
  5. Orekhova, N.A., Medvedev, E.V. and Konovalov, S.K., 2016. Carbonate System Characteristics of the Sevastopol Bay Waters in 2009–2015. Physical Oceanography, [e-journal] (3), pp. 36-46. doi:10.22449/1573-160X-2016-3-36-46
  6. Millero, F.J., 1996. Chemical Oceanography. 2nd ed. Boca Raton: CRC Press, 469 p.
  7. Riebesel, U., 2004. Effects of CO2 Enrichment on Marine Phytoplankton. J. Oceanogr., [e-journal] 60(4), pp. 719-729. doi:10.1007/s10872-004-5764-z
  8. Millero, F.J., 2007. The Marine Inorganic Carbon Cycle. Chem. Rev., [e-journal] 107(2), pp. 308-341. doi:10.1021/cr0503557
  9. Zeebe, R.E. and Wolf-Gladrow, D., 2001. CO2 in Seawater: Equilibrium, Kinetics, Isotopes. Elsevier Oceanography Series, 65. Amsterdam: Elsevier, 360 p. Available at: https://imedea.uib-csic.es/master/cambioglobal/Modulo_V_cod101611/Ocean%20Sinks/biblio/CO2Zeebe%26Wolf_Cap1.pdf [Accessed 11 October 2017].
  10. Heinze, C., Meyer, S., Goris, N., Anderson, L., Steinfeldt, R., Chang, N., Le Quéré, C. and Bakker, D.C.E., 2015. The Ocean Carbon Sink – Impacts, Vulnerabilities and Challenges. Earth Syst. Dynam., [e-journal] 6(1), pp. 327-358. doi:10.5194/esd-6-327-2015
  11. Bordovskiy, O.K. and Ivanenkov, V.N. eds., 1978. Metody Gidrokhimicheskikh Issledovaniy Okeana [Methods of Hydrochemical Ocean Studies]. Moscow: Nauka, 271 p. (In Russian).
  12. Bordovskiy, O.K. and Chernyakova, A.M. eds., 1992. Sovremennye Metody Gidrokhimicheskikh Issledovaniy Okeana [Modern Methods of Hydrochemical Ocean Studies]. Moscow: IO AN SSSR, 201 p. (in Russian).
  13. Unesco, 1987. Thermodynamic of the CO2 System. In: Unesco, 1987. Thermodynamic of the Carbon Dioxide System in Seawater. Unesco Technical Papers in Marine Science, 51. Paris: Unesco, pp. 3-21. Available at: http://www.jodc.go.jp/jodcweb/info/ioc_doc/UNESCO_tech/077668eb.pdf [Accessed 15 October 2017].
  14. Alekin, O.A. and Lyakhin, Yu.I., 1984. Khimiya Okeana [Ocean Chemistry]. Leningrad: Gidrometeoizdat, 340 p. (in Russian).
  15. Kuftarkova, E.A., Subbotin, A.A., Rodionova, N.Yu. and Ivanov, V.N., 2007. Ekologicheskie usloviya vyrashchivaniya midiy v Sevastopol'skoy bukhte [Ecological conditions for mussel growing in the Sevastopol Bay]. In: MHI NANU, 2007. Ekologicheskaya Bezopasnost' Pribrezhnykh i Shel'fovykh Zon i Kompleksnoe Ispol'zovanie Resursov Shel'fa [Ecological Safety of Coastal and Shelf Zones and Comprehensive Use of Shelf Resources]. ECOSI-Gidrofizika. Iss. 15, pp. 434-442 (in Russian).
  16. Sverdrup, H.U., Johnson, M.W. and Fleming, R.H., 1942. The Oceans: Their Physics, Chemistry and General Biology. New York: Prentice-Hall, Inc., 1087 p.
  17. Raymond, P.A., Bauer, J.E. and Cole, J.J., 2000. Atmospheric CO2 Evasion, Dissolved Inorganic Carbon Production, and Net Heterotrophy in the York River Estuary. Limnol. Oceanogr., [e-journal] 45(8), pp. 1707-1717. doi:10.4319/lo.2000.45.8.1707
  18. Borges, A.V., Schiettecatte, L.-S., Abril, G., Delille, B. and Gazeau, F., 2006. Carbon Dioxide in European Coastal Waters. Estuarine, Coastal and Shelf Science, [e-journal] 70(3), pp. 375-387. doi:10.1016/j.ecss.2006.05.046
  19. NOAA, 2018. NOAA Satellite and Information Service. [on-line] Available at: ftp://ftp.nodc.noaa.gov [Accessed 20 October 2017].

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