Temporal Variability of the Beryllium-7 (7Ве) Scavenging Ratio in the Sevastopol Region
D. A. Kremenchutskii
Marine Hydrophysical Institute of RAS, Sevastopol, Russian Federation
e-mail: t.malakhova@imbr-ras.ru
Abstract
Purpose. The study is purposed at identifying the features of temporal variability in the relation of 7Ве scavenging ratio at the seasonal and interannual time intervals depending on the amount and frequency of precipitation.
Methods and Results. The scavenging ratio was assessed based on the field data on the 7Ве concentration values in the atmosphere and precipitation in 2012–2020. Application of ANOVA made it possible to examine the relationship between the scavenging ratio and the variations in 7Be concentrations in the atmosphere and precipitation. The relationship between the scavenging ratio and the precipitation amount and frequency was studied by the correlation method of analysis.
Conclusions. The scavenging ratio values averaged over a season and a year varied within the ranges 423–1286 and 508–919, respectively. The geometric mean value of the scavenging ratio was 719+227-173. The intraannual variability of the scavenging ratio is absent at the 95% confidence level. The variability in average annual values of the scavenging ratio demonstrates a decrease in 2013 (as compared to 2012) from 664 to 508, an increase to 919 in 2016 and again a decrease to 516 in 2020. The ANOVA results indicate that variability of the scavenging ratio values averaged over a season and a year is due to the variation in 7Ве concentration in precipitation by 90 and 74%, respectively. In its turn, the long-term seasonal variability of 7Ве concentration in precipitation is conditioned by the variations in 7Ве concentration in the atmosphere (r = 0.64) and in the precipitation amount (r = −0.50). The relationship between the annual values of 7Ве concentration in precipitation and its concentration in the atmosphere or with the precipitation parameters has not been revealed. The correlation analysis results indicate that the variability of precipitation parameters (amount and frequency) produces no statistically significant effect at the 95% confidence level upon the variability of scavenging ratio values at seasonal and annual time intervals.
Keywords
Beryllium-7 (7Be), precipitation, atmospheric aerosol, scavenging ratio
Acknowledgements
The author is grateful to G. F. Batrakov, A. P. Arbuzova and T. M. Ivanova for their assistance in obtaining the data. The data for the study were obtained within the framework of state task of the Ministry of Science and Higher Education of Russian Federation (FNNN-2024-0001). Data analysis was carried out under the Russian Science Foundation grant (No. 22-77-10056).
Original russian text
Original Russian Text © D. A. Kremenchutskii, 2024, published in MORSKOY GIDROFIZICHESKIY ZHURNAL, Vol. 40, Iss. 2, pp. 271–283 (2024)
For citation
Kremenchutskii, D.A., 2024. Temporal Variability of the Beryllium-7 (7Ве) Scavenging Ratio in the Sevastopol Region, Physical Oceanography, 31(2), pp. 246-257.
References
- Lal, D. and Peters, B., 1967. Cosmic Ray Produced Radioactivity on the Earth. In: K. Sitte, ed., 1967. Kosmische Strahlung II / Cosmic Rays II. Handbuch der Physic / Encyclopedia of Physics, vol. 9/46/2. Berlin; Heidelberg: Springer, pp. 551-612. https://doi.org/10.1007/978-3-642-46079-1_7
- Zhang, F., Wang, J., Baskaran, M., Zhong, Q., Wang, Y., Paatero, J. and Du, J., 2021. A Global Dataset of Atmospheric 7Ве and 210Pb Measurements: Annual Air Concentration and Depositional Flux. Earth System Science Data, 13(6), pp. 2963-2994. https://doi.org/10.5194/essd-13-2963-2021
- Ioannidou, A., 2021. Activity Size Distribution of 7Ве in Association with Trace Metals in the Urban Area of the City of Thessaloniki, Greece. Atmospheric Environment, 45(6), pp. 1286-1290. https://doi.org/10.1016/j.atmosenv.2010.12.006
- Kadko, D., Landing, W.M. and Shelley, R.U., 2015. A Novel Tracer Technique to Quantify the Atmospheric Flux of Trace Elements to Remote Ocean Regions. Journal of Geophysical Research: Oceans, 120(2), pp. 848-858. https://doi.org/10.1002/2014JC010314
- Anderson, R.F., Cheng, H., Edwards, R.L., Fleisher, M.Q., Hayes, C.T., Huang, K.-F., Kadko, D., Lam, P.J., Landing, W.M. [et al.], 2016. How Well Can We Quantify Dust Deposition to the Ocean? Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, 374(2081), 20150285. https://doi.org/10.1098/rsta.2015.0285
- Kadko, D., Landing, W.M. and Buck, C.S., 2020. Quantifying Atmospheric Trace Element Deposition over the Ocean on a Global Scale with Satellite Rainfall Products. Geophysical Research Letters, 47(7), e2019GL086357. https://doi.org/10.1029/2019GL086357
- Kadko, D., Aguilar-Islas, A., Bolt, C., Buck, C.S., Fitzsimmons, J.N., Jensen, L.T., Landing, W.M., Marsay, C.M., Rember, R. [et al.], 2019. The Residence Times of Trace Elements Determined in the Surface Arctic Ocean during the 2015 US Arctic GEOTRACES Expedition. Marine Chemistry, 208, pp. 56-69. https://doi.org/10.1016/j.marchem.2018.10.011
- Kadko, D., Aguilar-Islas, A., Buck, C.S., Fitzsimmons, J.N., Landing, W.M., Shiller, A., Till, C.P., Bruland, K.W., Boyle, E.A. [et al.], 2020. Sources, Fluxes and Residence Times of Trace Elements Measured during the U.S. GEOTRACES East Pacific Zonal Transect. Marine Chemistry, 222, 103781. https://doi.org/10.1016/j.marchem.2020.103781
- Marsay, C.M., Kadko, D., Landing, W.M. and Buck, C.S., 2022. Bulk Aerosol Trace Element Concentrations and Deposition Fluxes during the U.S. GEOTRACES GP15 Pacific Meridional Transect. Global Biogeochemical Cycles, 36(2), e2021GB007122. https://doi.org/10.1029/2021GB007122
- Papastefanou, C., 2006. Radioactive Nuclides as Tracers of Environmental Processes. Journal of Radioanalytical and Nuclear Chemistry, 267(2), pp. 315-320. https://doi.org/10.1007/s10967-006-0050-8
- Lozano, R.L., San Miguel, E.G., Bolívar, J.P. and Baskaran, M., 2011. Depositional Fluxes and Concentrations of 7Ве and 210Pb in Bulk Precipitation and Aerosols at the Interface of Atlantic and Mediterranean Coasts in Spain. Journal of Geophysical Research: Atmospheres, 116(D18), D18213. https://doi.org/10.1029/2011JD015675
- Kremenchutskii, D.A., 2022. Precipitation Scavenging of Beryllium-7 (7Ве): Observation Results and Parameterization. Chemosphere, 307(2), 135908. https://doi.org/10.1016/j.chemosphere.2022.135908
- Chae, J.-S. and Kim, G., 2019. Large Seasonal Variations in Fine Aerosol Precipitation Rates Revealed Using Cosmogenic 7Ве as a Tracer. Science of The Total Environment, 673, pp. 1-6. https://doi.org/10.1016/j.scitotenv.2019.03.482
- Liu, G., Wu, J., Li, Y., Su, L. and Ding, M., 2020. Temporal Variations of 7Ве and 210Pb Activity Concentrations in the Atmosphere and Aerosol Deposition Velocity in Shenzhen, South China. Aerosol and Air Quality Research, 20(7), pp. 1607-1617. https://doi.org/10.4209/aaqr.2019.11.0560
- Kremenchutskii, D.A., 2022. Temporal Variability of Aerosol Wet Deposition Velocity in the Sevastopol Region: Observational Data. Physical Oceanography, 29(4), pp. 321-333.
- McNeary, D. and Baskaran, M., 2003. Depositional Characteristics of 7Ве and 210Pb in Southeastern Michigan. Journal of Geophysical Research: Atmospheres, 108(D7), 4210. https://doi.org/10.1029/2002JD003021
- Dueñas, C., Gordo, E., Liger, E., Cabello, M., Cañete, S., Pérez, M. and De La Torre-Luque, P., 2017. 7Ве, 210Pb and 40K Depositions over 11 Years in Málaga. Journal of Environmental Radioactivity, 178–179, pp. 325-334. https://doi.org/10.1016/j.jenvrad.2017.09.010
- Mohan, M.P., D’Souza, R.S., Nayak, S.R., Kamath, S.S., Shetty, T., Kumara, K.S., Mayya, Y.S. and Karunakara, N., 2019. Influence of Rainfall on Atmospheric Deposition Fluxes of 7Ве and 210Pb in Mangaluru (Mangalore) at the Southwest Coast of India. Atmospheric Environment, 202, pp. 281-295. https://doi.org/10.1016/j.atmosenv.2019.01.034
- Kremenchutskii, D.A. and Konovalov, S.K., 2022. Beryllium-7 (7Ве) and Its Variability in the Near-Surface Atmosphere of Crimea, the Black Sea Region. Atmospheric Pollution Research, 13(5), 101406. https://doi.org/10.1016/J.APR.2022.101406
- Kremenchutskii, D.A. and Batrakov, G.F., 2023. Seasonal Variations in Total Deposition Velocity and Washout Ratio of Fine Aerosols Revealed from Beryllium-7 (7Ве) Measurements in Sevastopol, the Black Sea Region. Atmospheric Pollution Research, 14(3), 101698. https://doi.org/10.1016/J.APR.2023.101698
- Carvalho, A.C., Reis, M., Silva, L. and Madruga, M.J., 2013. A Decade of 7Ве and 210Pb Activity in Surface Aerosols Measured over the Western Iberian Peninsula. Atmospheric Environment, 67, pp. 193-202. https://doi.org/10.1016/j.atmosenv.2012.10.060
- Efimov, V.V., Volodin, E.M., Anisimov, A.E. and Barabanov, V.S., 2015. Regional Projections of Climate Change for the Black Sea – Caspian Sea Area in Late XXI Century. Physical Oceanography, (5), pp. 49-66. https://doi.org/10.22449/1573-160X-2015-5-49-66
- Kremenchutskii, D.A., 2021. Influence of Precipitation on the Daily Beryllium-7 (7Ве) Activity Concentration in the Atmospheric Surface Layer. Journal of Environmental Radioactivity, 237, 106722. https://doi.org/10.1016/J.JENVRAD.2021.106722